The copper-promoted oxidative dehydrogenation and inner ring rearrangement of a macrocyclic ligand: the X-ray crystal structure of the resultant complex

Autor:	Ferida S. Esho, S. Martin Nelson, M.F. Cabral, Michael G. B. Drew, Joao de O. Cabral
Rok vydání:	1982
Předmět:	Schiff base Order (ring theory) chemistry.chemical_element Crystal structure Ring (chemistry) Photochemistry Copper Ion chemistry.chemical_compound Crystallography chemistry Molecular Medicine Dehydrogenation Macrocyclic ligand
Zdroj:	Journal of the Chemical Society, Chemical Communications. :1068
ISSN:	0022-4936
DOI:	10.1039/c39820001068
Popis:	The (7 + 12 + 7) inner ring system of a polycyclic Schiff base rearranges with accompanying oxidative dehydrogenation to a (15 + 6 + 3) inner ring system on reaction with Cu(ClO4)2.6H2O in the presence of dioxygen in order to accommodate the CuII ion within the 15-membered ring.
Databáze:	OpenAIRE
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