Reaction of alkyl- and arylamines with 2-(hydroxyimino)-3-oxobutanal

Autor: T. A. Frolenko, E. S. Semichenko, G. A. Suboch, Alexander A. Kondrasenko, A. A. Yarofeeva, O. A. Tsutsura
Rok vydání: 2017
Předmět:
Zdroj: Russian Journal of Organic Chemistry. 53:1-5
ISSN: 1608-3393
1070-4280
DOI: 10.1134/s1070428017010018
Popis: The condensation of 2-(hydroxyimino)-3-oxobutanal with primary aliphatic amines, cyclohexanamine, and amines containing an adamantane fragment afforded 4-(alkylamino)- and 4-(cyclohexylamino)-3- nitrosobut-3-en-2-ones. Analogous reaction with substituted anilines RC6H4NH2 (R = H, 4-Me, 4-OMe, 4-NH2, 4-Br, 4-I, 3-NO2) led to the formation of 4-aryl-3-hydroxyiminobutan-2-ones.
Databáze: OpenAIRE