Diels-Alder reactions of vinylbicyclo[4.1.0]heptenes

Autor: Jerrold Meinwald, Makoto Sakaino
Rok vydání: 1987
Předmět:
Zdroj: Tetrahedron Letters. 28:3201-3204
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)95471-6
Popis: Efficient syntheses of 1,3-dimethy1-2-vinylbicyclo[4.1.0]hept-2-ene (1) and 2,2-ethylenedioxy-4,6-dimethyl-5-vinylbicyclo[4.1.0]hept-4-ene (2) are described. These dienes, which undergo Diels-Alder reactions with p -benzoquinones readily, may serve as versatile intermediates for terpenoid synthesis.
Databáze: OpenAIRE