Heterobimetallorganische 1,2-(N,N-Dimethylaminomethyl)ferrocenyl-Derivate des vier- und zweiwertigen Zinns: Synthesen, Charakteristika und Kristallstrukturen

Autor:	Marco Fontani, Emanuela Grigiotti, Jaroslav Holeček, Klaus Jacob, Antonín Lyčka, Naka Seidel, Axel Fischer, Frank Voigt, Piero Zanello, Claus Pietzsch
Rok vydání:	2000
Předmět:	chemistry Mössbauer spectroscopy Inorganic chemistry Proton NMR chemistry.chemical_element Chelation Lithium Cyclic voltammetry Tin Spectroscopy Medicinal chemistry Single crystal
Zdroj:	Journal für praktische Chemie. 342:574-584
ISSN:	1521-3897 1436-9966
Popis:	SnCl4 reacts with [1,2-(N,N-dimethylaminomethyl) ferrocenyl]lithium (FcNLi) under formation of the organo tin compounds of the four valued tin (FcN)n SnCl 4-n [n = 1(1), 2(2), 3(3), 4(4)]. The heterobimetallic chelate complex bis[1,2-(N,N-dimethylaminomethyl)ferrocenyl]tin(II) (FcN)2 Sn (5) is formed at the reaction of SnCl2 with two equivalents of FcNLi. The heterobimetallic tin compounds 1 — 5 were characterized by 1H NMR-, 13C-NMR and mass spectroscopy, single crystal x-ray analyses (1,3,4,5), 57 Fe-Moessbauer spectroscopy (1, 3, 4, 5), respectively cyclic voltammetry.
Databáze:	OpenAIRE
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