Synthesis, Characterization and Reactions of Enantiomerically Pure ‘Winged’ Spirane Porphyrazines

Autor:	Andrew Simon Cook, Antonio Garrido Montalban, Anthony G. M. Barrett, Shun ichiro Hachiya, D. Bradley G. Williams, Brian M. Hoffman
Rok vydání:	2000
Předmět:	Organic Chemistry Tartrate Biochemistry Asymmetric induction Medicinal chemistry Catalysis Styrene Transmetalation chemistry.chemical_compound Oxygen atom chemistry Sodium hypochlorite Drug Discovery Organic chemistry
Zdroj:	Tetrahedron. 56:6565-6569
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(00)00607-4
Popis:	A series of enantiomerically pure porphyrazineoctaol derivatives have been prepared from l -(+)-dimethyl tartrate via conversion into the corresponding dispoke protected dihydroxymaleonitrile, Linstead macrocyclization and transmetallation. The derived chloromanganese(III) complexes catalyzed the epoxidation of styrene with sodium hypochlorite as the oxygen atom source but with modest enantioselectivities (
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::01cc11d35da39ef797b9b2c46e4e4156 https://doi.org/10.1016/s0040-4020(00)00607-4 Zobrazit plný text záznamu Full Text from ScienceDirect