Electronic structure of α and γ phases of Si(111)––Sn

Autor: Anne Charrier, J.-M. Themlin, F. Thibaudau, J.-M. Debever, I. Forbeaux
Rok vydání: 2000
Předmět:
Zdroj: Applied Surface Science. :375-379
ISSN: 0169-4332
DOI: 10.1016/s0169-4332(00)00218-x
Popis: This work presents a detailed comparison of the electronic properties of two phases (α and γ) of the prototypical Si(111)– 3 × 3 –Sn system, focussing on the empty surface states. The latter reconstruction has been studied at room temperature with inverse photoemission (KRIPES). For the γ-phase characterised by an equal amount of Sn and Si adatoms, a charge transfer towards the Sn adatom leaves an empty surface state localised on Si adatoms, and observed in KRIPES 0.4 eV above the Fermi level (EF) at the surface Brillouin zone (SBZ) center. The band gap of this semiconducting γ-phase is estimated around 0.5 eV. In contrast, the α phase with only Sn adatoms shows a metallic behaviour and two distinct adatom-derived empty surface states.
Databáze: OpenAIRE