Meso pyridin-4-ylsulfanyl substituted doubly N-confused pentafluorophenyl[26]hexaphyrin

Autor: F. Figueira, Filipe A. Almeida Paz, João P. C. Tomé
Rok vydání: 2023
Předmět:
Zdroj: Journal of Porphyrins and Phthalocyanines. :A-G
ISSN: 1099-1409
1088-4246
DOI: 10.1142/s1088424623500244
Popis: In recent years, much attention has been devoted to synthesizing and preparing novel expanded porphyrin architectures. Here we report the selective substitution of the [Formula: see text]-fluorine atoms of meso-hexakis(pentafluorophenyl)[Formula: see text]-confused[26]hexaphyrin with six 4-mercaptopyridine moieties. The preparation methods here described opening an avenue towards the modification and application of these macrocycles in a wide array of applications such as catalysis, sensing, and photonic applications.
Databáze: OpenAIRE