A mass-spectral study ofexo- andendo-2-norbornyl bromide andexo andendo-8-bromobicyclo[3.2.1]octane by photoionization
| Autor: | J. H. Beynon, Don C. DeJongh, S. R. Shrader, N. A. LeBel, R. G. Isakson |
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| Rok vydání: | 1969 |
| Předmět: |
Relative intensity
Chemistry fungi food and beverages macromolecular substances Photoionization Photochemistry Biochemistry 2-Norbornyl cation carbohydrates (lipids) enzymes and coenzymes (carbohydrates) chemistry.chemical_compound Bromide Mass spectrum Molecular Medicine Solvolysis Instrumentation Spectroscopy Octane |
| Zdroj: | Organic Mass Spectrometry. 2:919-922 |
| ISSN: | 1096-9888 0030-493X |
| DOI: | 10.1002/oms.1210020908 |
| Popis: | The photoionization, as well as the electron-impact, mass spectra of exo-and endo-norbornyl bromide and of exo-and endo-8-bromobicyclo[3.2.1]octane show that exo-Br loss is more facile than endo-Br loss in formation of C7H11⊕ and C8H13⊕, respectively. The relative intensity values are compared with solvolysis data from the same systems. |
| Databáze: | OpenAIRE |
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