Ionic liquids used as a green approach in headspace single drop microextraction and GCMS determination of organotin compounds

Autor: Georgieva, Lora I., Román Falco, Iván, Stefanova, Violeta M., Kmetov, Veselin Y., Canals, Antonio
Přispěvatelé: Universidad de Alicante. Departamento de Química Analítica, Nutrición y Bromatología, Espectroscopía Atómica-Masas y Química Analítica en Condiciones Extremas
Jazyk: angličtina
Rok vydání: 2012
Předmět:
Zdroj: RUA. Repositorio Institucional de la Universidad de Alicante
Universidad de Alicante (UA)
Popis: Gas chromatography with MS detection was applied for simultaneous determination of six of the most toxic organotin compounds (OTs): monobutyltin, dibutyltin, tributyltin, monophenyltin, diphenyltin, triphenyltin. Headspace single drop microextraction (HS-SDME) in Ionic liquids (ILs) was proposed as Green alternative to the traditional one. Three different ILs ([C8MIM][PF6]; [C6MIM][PF6]) and [C4MIM][PF6]) were evaluated as a collector phase. The first one was found as the most appropriate for a group microextraction of the tested OTs. Analytes were evaporated from the IL microdrop by means of thermal desorption. ILs possess some advantages as an extraction phase in comparison with traditionally used organic solvents. They are more stable during the analytical process and are considered as environmentally friendly compounds. Moreover HS-SDME procedure was performed in a single drop of only 5μl IL. The time needed for the extraction was proved to be only 20 min. Therefore the proposed method could be related to the Green chemistry methods. The current study has been financially supported by: NSF of Bulgaria (Project DO 02-70 (GAMA)); EC 7FP Project 245588 (BioSupport); MICINN of Spain (Project CTQ2008-06730-C02-01) and Regional Government of Valencia (Project ACOMP2010/047). LG thanks Erasmus program and Ministry of Education for her fellowship. IPR also thanks “Caja de Ahorros del Mediterraneo (CAM)” for his Ph.D fellowship.
Databáze: OpenAIRE
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