Six-membered cyclic semiaminal as intermediate in the synthesis of thiazoles from thiosemicarhazide and α-haloketones
| Autor: | Mamedov V., Berdnikov E., Valeeva V., Ismaev I., Rizvanov I., Antokhina L., Nuretdinov I., Chernov P. |
|---|---|
| Rok vydání: | 1993 |
| Předmět: | |
| Zdroj: | SCOPUS10665285-1993-42-11-SID25444440955 |
| Popis: | Cyclization of thiosemicarbazide with methyl 3-chloro-2-oxo-3-phenylpropionate in MeCN results in 5-hydroxy-2-imino-5-methoxycarbonyl-6-phenylperhydro-1,3,4-thiadiazine. The structure of the product has been confirmed using spectral (IR,1H,13C,13C{1H} NMR) methods and chemical transformations. © 1994 Plenum Publishing Corporation. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|