Chemioselective reactions of N1-methyl-2-hydroxy-3-methylamino-3-phenylpropanamide with electrophiles

Autor:	Hajji C., Testa M.L., Zaballos-Garcma E., Zaragoza R. J., Server-Carris J., Sepzlveda-Arques J.
Rok vydání:	2002
Předmět:	Crystal structure Density functional theory Electrophiles Molecular structure
Zdroj:	58 (2002): 3281–3285. info:cnr-pdr/source/autori:Hajji C., Testa M.L., Zaballos-Garcma E., Zaragoza R. J., Server-Carris J., Sepzlveda-Arques J./titolo:Chemioselective reactions of N1-methyl-2-hydroxy-3-methylamino-3-phenylpropanamide with electrophiles/doi:/rivista:/anno:2002/pagina_da:3281/pagina_a:3285/intervallo_pagine:3281–3285/volume:58
Popis:	The reactivity of (-)-(aS,bS)-a-Hydroxy-N-methyl-b-(methylamino)benzenepropanamide w (contg. three nucleophilic centers) was studied against dihaloalkanes and aldehydes. Hexahydro-4-pyrimidinones or oxazolidines were obtained chemoselectively. Exptl. results were explained by ab initio calcns
Databáze:	OpenAIRE
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