| Autor: |
Alexander, MJ, Bowie, JH, Hayes, RN |
| Zdroj: |
Australian Journal of Chemistry; 1990, Vol. 43 Issue: 12 p2027-2034, 8p |
| Abstrakt: |
Rearrangement reactions involving hydride and methyl anion migrations are observed when certain enolate ions derived from isopropyl and t- butyl ketones are subjected to collisional activation. For example (i) -CH2CO-i-C3H7 → -(CH2CHO)+C3H6and (ii) -CH2CO-t-C4H9 → -(CH2COCH3)+C3H6The mechanisms of these and related reactions have been investigated by denterium labelling and product ion studies. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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