The isomerization, catalysed by boron trichloride, of 2-methylbut-1-ene.

Autor: Cameron, GS, Stimson, VR
Zdroj: Australian Journal of Chemistry; 1977, Vol. 30 Issue: 4 p923-925, 3p
Abstrakt: Boron trichloride (2% in carbon dioxide) catalyses the isomerization of 2-methylbut-1-ene to 2-methylbut-2-ene at 368-467 with k2 = 109.71exp(-91460/8.314T) s-1 ml mol-1 Gas-phase isomerization catalysed by Lewis acids is thus extended to olefins.
Databáze: Supplemental Index