Autor: |
Graddon, DP, Prakash, S |
Zdroj: |
Australian Journal of Chemistry; 1974, Vol. 27 Issue: 10 p2099-2102, 4p |
Abstrakt: |
Thermodynamic data have been obtained for the formation in benzene solution of adducts of nickel(11) O-alkylxanthate complexes with one molecule of 2,2'-bipyridine or two molecules of pyridine or 4-methylpyridine. The results show that changes in the free energy and enthalpy of adduct formation with variation of the alkyl group in the xanthate can be explained wholly by inductive effects; there is no evidence for steric effects even with branched alkyl chains. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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