Measurement of the O2 (b1Sg+ a1Dg) transition probability by the method of intracavity laser spectroscopy

Autor: Vagin, Nikolai P., Ionin, Andrei A., Kochetov, I.V., Napartovich, A.P., Podmar'kov, Yu.P., Frolov, M.P., Yuryshev, Nikolai N.
Zdroj: Quantum Electronics; June 2005, Vol. 35 Issue: 4 p378-384, 7p
Abstrakt: The method of intracavity laser spectroscopy using a Co:MgF2 laser is applied to record the absorption spectra from the first excited a1Dg state of gaseous molecular oxygen at the a1Dg b1Sg+ transition at 1.91 mm. The gas flow from a chemical singlet oxygen generator with a known concentration of singlet oxygen O2 (a1Dg) was supplied to the cavity of the Co:MgF2 laser. The absorption line intensities are measured for five spectral lines of the Q-branch of the 0—0 vibrational band for the a1Dg b1Sg+ transition. The O2 (b1Sg+ a1Dg) transition probability calculated from these data was (1.20 ± 0.25) × 10-3 s-1.
Databáze: Supplemental Index