Spatial and seasonal dynamics of gaseous elemental mercury concentrations over Switzerland observed by a passive air sampler networkElectronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d4ea00052h

Autor: Osterwalder, Stefan, Schibler, Ron, Hüglin, Christoph, Schwarzenbach, Beat, Stupple, Geoff, MacSween, Katrina, Bishop, Kevin, Alewell, Christine, Buchmann, Nina
Zdroj: Environmental Science: Atmospheres; 2024, Vol. 4 Issue: 8 p848-860, 13p
Abstrakt: Mercury (Hg) is a threat to the environment and human health. As a consequence, the Minamata Convention on Mercury was adopted in 2013 to reduce Hg pollution by curbing anthropogenic emissions. Analysis of gaseous elemental Hg (Hg0) concentration trends in the atmosphere has been identified as a cost-effective means to evaluate progress on reducing Hg pollution. Therefore, spatial coverage of atmospheric Hg0concentration measurements should be expanded. We established an atmospheric Hg0concentration monitoring network with 22 sites across Switzerland, using the Mercury Passive Air Sampler (MerPAS®). The mean annual atmospheric Hg0concentration in Switzerland was 1.34 ± 0.20 ng m−3(August 22, 2022 – September 21, 2023), similar to current observations at European air monitoring stations. Mean atmospheric Hg0concentrations were significantly lower at rural stations (1.25 ± 0.11 ng m−3) than at urban (1.37 ± 0.14 ng m−3) stations (Mann-Whitney U-test, p< 0.01). This concentration difference can be explained by more local Hg emissions at urban sites (e.g., by fuel combustion) throughout the year as well as by more pronounced stomatal Hg0uptake at rural sites during spring and summer. We recommend continuing the Swiss Atmospheric Mercury Network to support the call from the Minamata Convention to monitor atmospheric Hg0as a control on whether international efforts are successful in reducing Hg in the environment. Longer term records from such monitoring networks will also help improve the understanding of both regional and global Hg cycles.
Databáze: Supplemental Index