Autor: |
Kobayashi, Michio, Nishi, Ritsuko, Minato, Hiroshi |
Zdroj: |
Bulletin of the Chemical Society of Japan; April 1974, Vol. 47 Issue: 4 p888-890, 3p |
Abstrakt: |
The rates of hydrolysis of ethyl p-substituted benzenesulfinates were determined in acidic and alkaline media; the rates were greater in the former with the sulfinates containing electron-releasing substituents, ?=-0.54 (20°C); and in the latter with the sulfinates containing electron-withdrawing substituents, ?=1.60. The mechanisms of the hydrolysis are discussed. |
Databáze: |
Supplemental Index |
Externí odkaz: |
|