Kinetic Studies on the Hydrolysis of Ethyl Benzenesulfinates

Autor: Kobayashi, Michio, Nishi, Ritsuko, Minato, Hiroshi
Zdroj: Bulletin of the Chemical Society of Japan; April 1974, Vol. 47 Issue: 4 p888-890, 3p
Abstrakt: The rates of hydrolysis of ethyl p-substituted benzenesulfinates were determined in acidic and alkaline media; the rates were greater in the former with the sulfinates containing electron-releasing substituents, ?=-0.54 (20°C); and in the latter with the sulfinates containing electron-withdrawing substituents, ?=1.60. The mechanisms of the hydrolysis are discussed.
Databáze: Supplemental Index