ON THE CARBON MONOXIDE ADDUCT FORMATION OF A COBALT–TETRAOXIME COMPLEX
| Autor: | Backes, Joseph, Masuda, Isao, Shinra, Koichiro |
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| Zdroj: | Chemistry Letters; May 1972, Vol. 1 Issue: 5 p361-364, 4p |
| Abstrakt: | In a hydrazine hydrate/DMA solution CoCl2·6H2O and CH3C(NOH)C(NOH)–(CH2)10–C(NOH)C(NOH)CH3were found to absorb up to 0.5 mole of CO per 1 mole of cobaltous ion to form a CO adduct which releases CO in air to give a Co(II)–tetraoxime complex. A Co(I)-tetraoxime intermediate is considered to be the reactive species toward CO. |
| Databáze: | Supplemental Index |
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