Autor: |
Ueoka, Ryuichi, Goto, Kouichi, Tanoue, Osamu, Miki, Atsushi, Yoshimitsu, Shinya, Imamura, Chikara, Ihara, Yasuji, Murakami, Yukito |
Zdroj: |
Chemistry Letters; January 1999, Vol. 28 Issue: 1 p73-74, 2p |
Abstrakt: |
The diastereoselectivity for the hydrolysis of p-methoxycarbonylphenyl N-(benzyloxycarbonyl)-D(L)-phenylalanyl-L-leucinate in aqueous solution was inverted by changing concentrations of the substrates or the reaction temperature. The monomer-aggregate transition operated on the LL-substrate, which was suggested by the spectroscopic measurements, seems to be responsible for such behavior. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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