Autor: |
Bowen, T. C., Wyss, J. C., Noble, R. D., Falconer, J. L. |
Zdroj: |
Industrial & Engineering Chemistry Research; May 2004, Vol. 43 Issue: 10 p2598-2601, 4p |
Abstrakt: |
Coadsorbed molecules in a ZSM-5 zeolite are directly shown to decrease or increase the diffusion rates of each other at high coverages. For an ethanol/methanol mixture, ethanol diffused faster and methanol slower than the corresponding pure material. For an acetone/methanol mixture, however, both molecules diffused slower than pure acetone, which is the slower diffusing molecule. Diffusion rates were directly measured at steady-state conditions using liquid feeds and isotopic labeling during transient permeation through a ZSM-5 zeolite membrane. |
Databáze: |
Supplemental Index |
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