Mercury removal from aqueous solution using petal-like MoS2nanosheets

Autor: Pirarath, Ragini, Shivashanmugam, Palani, Syed, Asad, Elgorban, Abdallah M., Anandan, Sambandam, Ashokkumar, Muthupandian
Zdroj: Frontiers of Environmental Science & Engineering; February 2021, Vol. 15 Issue: 1
Abstrakt: Recently, different nanomaterial-based adsorbents have received greater attention for the removal of environmental pollutants, specifically heavy metals from aqueous media. In this work, we synthesized few-layered MoS2nanosheets via a surfactant-assisted hydrothermal method and utilized them as an efficient adsorbent for the removal of mercury from aqueous media. The synthesized MoS2nanosheets showed petal-like morphology as confirmed by scanning electron microscope and high-resolution transmission electron microscopic analysis. The average thickness of the nanosheets is found to be about 57 nm. Possessing high stability and negative zeta potential makes this material suitable for efficient adsorption of mercury from aqueous media. The adsorption efficiency of the adsorbent was investigated as a function of pH, contact time and adsorbent dose. The kinetics of adsorption and reusability potential of the adsorbent were also performed. A pseudo-second-order kinetics for mercury adsorption was observed. As prepared MoS2nanosheets showed 93% mercury removal efficiency, whereas regenerated adsorbent showed 91% and 79% removal efficiency in the respective 2ndand 3rdcycles. The adsorption capacity of the adsorbent was found to be 289 mg/g at room temperature.
Databáze: Supplemental Index