| Autor: |
Kurian, Jais, Shurooque, Kanneth S., Ramkumar, Venkatachalam, Chakkumkumarath, Lakshmi, Kannoth M., Muraleedharan |
| Zdroj: |
Organic Letters; May 2021, Vol. 23 Issue: 9 p3354-3358, 5p |
| Abstrakt: |
A new class of cyclazine analogues with periphery reminiscent of an aza[10]annulene framework, tethered internally by an sp3carbon, is presented. In depth structure analysis based on NMR and X-ray diffraction data gave a deeper insight into the effect of electron delocalization on their structure and properties. A characteristic change in chemical shift positions suggested an aromatic ring current in these systems. Attractive emission properties in solid and solution states involving charge transfer is another highlight. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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