Investigation of the Substrate/Epitaxial Interface of Si/Si1-xGexLayers Grown by LPCVD

Autor: Loo, R., Vescan, L., Dieker, C., Freundt, D., Hartmann, A., Mück, A., Loo, R., Vescan, L., Dieker, C., Freundt, D., Hartmann, A., Mück, A.
Zdroj: Journal de Physique IV - Proceedings; June 1995, Vol. 5 Issue: 1 pC5-895-C5-903, 8955899p
Abstrakt: The paper reports a study of the quality of the substrate/epilayer interface. Before growing the Si or Si/Si1-xGexstructures by low pressure chemical vapour deposition, Si(100) substrates were cleaned by a modified RCA-cleaning and just before epitaxy different ex-situ and in-situ processes were applied to remove the oxide layer grown on the wafer substrates in the last step of the RCA-cleaning. The effect of interfacial contamination on electrical and optical properties were studied. By a wet-chemical removal of the oxide layer an interfacial oxygen level of 1.3x1013atoms/cm2is found, while a thermal removal leads to an interfacial oxygen level below 6x1012atoms/cm2. In both cases carbon levels of (1-2)x1014atoms/cm2have been detected. By electrochemical capacitance-voltage profiling it was found that these contaminations are connected with electrically active donors. According to our investigations, electrochemical capacitance-voltage profiling is suitable to give a quick indication on the quality of the substrate/epitaxial interface. In addition, the removal of the oxide layer was investigated by high resolution electron energy loss spectroscopy on cleaned Si-surfaces.
Databáze: Supplemental Index