| Autor: |
Lyubovskii, R. B., Lyubovskaya, R. N., Dyachenko, O. A., Gritsenko, V. V., Makova, M. K., Merzhanov, V. A., Lyubovskii, R. B., Lyubovskaya, R. N., Dyachenko, O. A., Gritsenko, V. V., Makova, M. K., Merzhanov, V. A. |
| Zdroj: |
Journal de Physique I; December 1993, Vol. 3 Issue: 12 p2411-2416, 6p |
| Abstrakt: |
The deuterated organic salt based on (d8-ET) (ET is bis(ethylenedithio) tetrathiafulvalene (BEDT-TTF)) was synthesized with bromine-mercurate anion. X-ray crystallographic studies have demonstrated it to have the following formula, κ-(d8-ET)4(HgBr2. Hg2Br6). Various types of the temperature dependences of conductivity for the crystals from the same batch have been found but not one of the studied samples was a superconductor at ambient pressure. All crystals studied at ambient pressure seem to become superconductors at low pressure (~300 bar) with different Tc. Crystal structure features of this salt with d8-ET cation are compared with the structure of an organic superconductor (ET)4Hg2.89Br8at ambient pressure. The differences in their superconducting properties are associated with high lability of Hg-containing salts. |
| Databáze: |
Supplemental Index |
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