Autor: |
Dedyukhin, Alexander S., Shchetinskiy, Andrey V., Kharina, Ekaterina A., Shchepin, Ivan E., Volkovich, Vladimir A., Yamshchikov, Leonid F., Osipenko, Alexandr G. |
Zdroj: |
ECS Transactions; August 2016, Vol. 75 Issue: 15 p265-274, 10p |
Abstrakt: |
The behavior and properties of lanthanum in a "molten salt - liquid metal" system in relation to pyrochemical reprocessing of spent nuclear fuels was considered. Temperature dependencies of lanthanum formal standard electrode potential E*La/La(III) and Gibbs free energy change of lanthanum trichloride formation in LiCl-KCl-CsCl eutectic based melts were obtained between 668-976 K. Also the behavior of lanthanum was studied in Ga-Al (1.6 wt. % Al) and Ga-Zn (3.64 wt. % Zn) eutectic based metallic alloys, and activity, solubility and activity coefficients of lanthanum determined. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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