| Autor: |
Mallick, Sudesh, Maddala, Sudhakar, Kollimalayan, Kalidass, Venkatakrishnan, Parthasarathy |
| Zdroj: |
The Journal of Organic Chemistry; December 2018, Vol. 84 Issue: 1 p73-93, 21p |
| Abstrakt: |
Oxidative C–C coupling of carbazoles possessing various substituents is demonstrated in the presence of organic (metal-free) recyclable oxidants, such as DDQ or CA/H+, for accessing bicarbazole regioisomers. Differently substituted carbazoles are examined to showcase regioselective discrimination (3,3′- versus 1,3′-bicarbazoles) and preferences based on sterics and electronics in oxidative coupling. Finally, a mechanism that involves the carbazole radical cation has been traced (evidenced) and proposed on the basis of the UV–vis–NIR absorption and EPR spectroscopy results. This study underlines the strategic chemical preparation of a series of bicarbazoles in an efficient manner. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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