Studies towards the synthesis of the marine metabolite, octalactin A
Autor: | Hulme, Alison N., Howells, Garnet E. |
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Zdroj: | Tetrahedron Letters; January 1997, Vol. 38 Issue: 47 p8245-8248, 4p |
Abstrakt: | Studies towards the synthesis of the marine metabolite octalactin A 1, are described. Key steps in this strategy include an antialdol reaction to set the C 7C 8stereochemistry, Horner Wadsworth Emmons coupling to give the trisubstituted E-double bond and a novel samarium-mediated cyclisation reaction. |
Databáze: | Supplemental Index |
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