First example of 1,1-bimetalloalkenes of tellurium and zirconium: Application for stereoselective preparation of (Z)-α-organotelluro-α,β-unsaturated carbonyl compounds
| Autor: | Sung, Jin Wuk, Jang, Won Bum, Oh, Dong Young |
|---|---|
| Zdroj: | Tetrahedron Letters; January 1996, Vol. 37 Issue: 42 p7537-7540, 4p |
| Abstrakt: | Hydrozirconation of acetylenic tellurides 1affords the first examples of 1,1-bimetalloalkenes of tellurium and zirconium 2. Intermediates 2are reacted with acyl halides to obtain (Z)-α-organotelluro- α,β-unsaturated carbonyl compounds 4via ZrCu transmetallation. |
| Databáze: | Supplemental Index |
| Externí odkaz: |
|
Full Text from ScienceDirect