Synthesis and crystal structure of a 3D copper(II)–silver(I) coordination polymer assembled through hydrogen bonding, π–πstacking and metal–πinteractions, {[Cu(phen)2(CN)][Ag(CN)2] · 3H2O}n(phen = 1,10-phenanthroline)

Autor: Nawaz, Sidra, Rüffer, Tobias, Lang, Heinrich, Shaheen, Muhammad Ashraf, Ahmad, Saeed, Shah, Javed Hussain
Zdroj: Zeitschrift für Naturforschung B; July 2015, Vol. 70 Issue: 7 p455-459, 5p
Abstrakt: A copper(II) polymeric complex {[Cu(phen)2(CN)][Ag(CN)2] · 3H2O}n, 1(phen = 1,10-phenanthroline), has been prepared and structurally characterized. The compound crystallizes in the monoclinic space group P21/cwith [Cu(phen)2(CN)]+and [Ag(CN)2]−units and three water molecules. The cationic and anionic units are linked to each other through M-πand π–πinteractions. The array is extended further by hydrogen bonding and π–πinteractions to form a 3D network.
Databáze: Supplemental Index