Abstrakt: |
Several routes for the synthesis of N-pentamethyldisilanylphosphine imines have been investigated. The title compounds may be prepared by methylation of N-(2-chlorodisilanyl)-phosphine imines, from tertiary phosphines and pentamethyldisilanyl azide, from triorganophosphine imines and pentamethyldisilanyl chloride, or, by transsilylation, from the corresponding N-trimethylsilylphosphine imines. 22 new compounds were characterized by elemental analysis, molecular weights, IR and NMR spectra. |