[(TM EDA)2Li4Cl4(H2O)2]·2 TMEDA: stabförmige vierkernige Li-Komplexe verknüpft durch TMEDA / [(TM EDA)2Li4Cl4(H2O)2]·2TMEDA: Stick-Like Tetranuclear Li Complexes Connected by TMEDA

Autor: Werner, Bert, Neumüller, Bernhard
Zdroj: Zeitschrift für Naturforschung B; September 1995, Vol. 50 Issue: 9 p1348-1352, 5p
Abstrakt: The title compound 1 was synthesized by the reaction of LiCl with TM EDA (N,N,N′,N′- tetramethylethylendiamine) and water at 120 °C in boiling TM EDA. 1 was crystallized at - 30 °C as colorless crystals and characterized by NMR and IR spectroscopy as well as by an X-ray structure determination. 1 is a polymer in the solid state, built up by an alternating arrangement of stick-like tetranuclear Li complexes and two TMEDA molecules. The complexes and the TMEDA molecules are connected by hydrogen bridges in infinite chains.
Databáze: Supplemental Index