New routes to high nuclearity cages: dimerisation of a manganese triangle viasolvothermal synthesis

Autor: Low, David M., Brechin, Euan K., Helliwell, Madeleine, Mallah, Talal, Rivière, Eric, McInnes, Eric J. L.
Zdroj: Chemical Communications; 2003, Vol. 2003 Issue: 18 p2330-2331, 2p
Abstrakt: Heating Mn3OO2CPh6py2H2O in MeCN at 100 °C for 12 hours in a sealed Teflon container produces the hexanuclear species Mn6O2O2CPh12py2: dimerisation of the triangle occurs viasolvent loss and ligand rearrangement.
Databáze: Supplemental Index