Diastereo- and Enantioselective Intramolecular C(sp3)—H Arylation for the Synthesis of Fused Cyclopentanes
| Autor: | Martin, Nicolas, Pierre, Cathleen, Davi, Michaël, Jazzar, Rodolphe, Baudoin, Olivier |
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| Zdroj: | Chemistry - A European Journal; April 2012, Vol. 18 Issue: 15 p4480-4484, 5p |
| Abstrakt: | All CH bonds are not equal: The intramolecular arylation of unactivated C(sp3)H bonds in the presence of a chiral Pd/binepine catalyst allows the synthesis of fused cyclopentanes efficiently and in an diastereo‐ and enantioselective manner (see scheme). |
| Databáze: | Supplemental Index |
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