Molecular structure of CH(GeBr3)3determined by gas electron diffraction and ab initio calculations: steric congestion in tri- and tetra-germylmethanes

Autor:	Haaland, A., Shorokhov, D.J., Volden, H.V., McMurran, J., Kouvetakis, J.
Zdroj:	Journal of Molecular Structure; October 1999, Vol. 509 Issue: 1-3 p29-34, 6p
Abstrakt:	The molecular structure of CH(GeBr3)3has been determined by gas electron diffraction (GED) and ab initio calculation at the HF/6-31G∗level. The calculations indicate that the equilibrium structure has C3symmetry. The most important bond distances are (GED/HF-MO); Ge–C=199.5(10)/193.6pm, Ge–Br (mean)=228.1(2)/228.0pm, and valence angles
Databáze:	Supplemental Index
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