| Autor: |
Fukin, Georgy K., Zakharov, Lev N., Maslennikov, Stanislav V., Piskunov, Alexander V., Cherkasov, Vladimir K. |
| Zdroj: |
Acta Crystallographica Section C: Crystal Structure Communications; September 2001, Vol. 57 Issue: 9 p1020-1021, 2p |
| Abstrakt: |
X‐ray diffraction shows that the title cadmium(II) complex, [Cd2(C14H20O2)2(C5H5N)6]·2C5H5N, has a dimeric structure in which two (py)3Cd(3,5‐di‐tert‐butylcatecholate) units (py is pyridine) are connected by two bridging O atoms, the coordination of the Cd atoms being distorted octahedral. There are two symmetrically independent dimers in the crystal structure; one is in a general position and the other lies about an inversion centre. In both cases, the bridging Cd—O distances between the Cd–catecholate units [2.224 (2)–2.237 (2) Å] are shorter than the bridging Cd—O distances within the catecholate cycle [2.273 (2)–2.281 (2) Å]. The Cd—Npydistances are 2.354 (2)–2.471 (2) Å. Besides the main molecules, the crystal also contains pyridine solvate molecules. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
|
Plný text