Synthesis and structure of new triphenylphosphine π-complexes of palladium(0) with p-benzoquinone and their role in the oxidative carbonylation of alkynes

Autor:	Kulik, Alexander V., Bruk, Lev G., Temkin, Oleg N., Khabibulin, Vildar R., Belsky, Vitaly K., Zavodnik, Valery E.
Zdroj:	Mendeleev Communications; April 30, 2002, Vol. 12 Issue: 2 p47-48, 2p
Abstrakt:	The complexes [Pd(η2-Q)(PPh3)2]2H2Q and Pd2(μ-η2,η2-Q)2(PPh3)2 (where Q and H2Q are p-benzoquinone and hydroquinone, respectively) were synthesised and structurally characterised, and their catalytic activity in the oxidative carbonylation of phenyl-acetylene to methyl phenylpropiolate was examined.
Databáze:	Supplemental Index
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