| Autor: |
Robin, S., Guerret, O., Couturier, J.-L., Pirri, R., Gnanou, Y. |
| Zdroj: |
Macromolecules; May 2002, Vol. 35 Issue: 10 p3844-3848, 5p |
| Abstrakt: |
This study investigates the ability of a novel difunctional alkoxyamine based on N-tert-butyl-1-diethylphosphono-2,2-dimethylpropyl nitroxide (SG1) to serve as initiator for the controlled radical polymerization of styrene (S) and n-butyl acrylate (nBuA). The efficiency of this initiator was checked using three different methods. After we set up the conditions best suited to the synthesis of perfectly difunctional poly(n-butyl acrylate) (PnBuA) samples, well-defined poly(styrene-b-n-butyl acrylate-b-styrene) triblock copolymers could be obtained by sequential polymerization of the corresponding monomers. However, a loss of control of the targeted structure was observed whenever the conversion of styrene exceeded 40%. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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