| Autor: |
Olivato, P. R., Viertler, H., Wladislaw, B., Cole, K. C., Sandorfy, C. |
| Zdroj: |
Canadian Journal of Chemistry; October 1976, Vol. 54 Issue: 19 p3026-3030, 5p |
| Abstrakt: |
Photoelectron spectra show that in CH3SCH2COCH3the sulfur and carbonyl lone pair orbitals are both stabilized with respect to the compounds containing S or CO only. This is in keeping with the observed values of the basicity constants. The ultraviolet absorption spectra contain the expected and bands and give evidence for a significant amount of mixing between the excited orbitals. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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