1H NMR Study of Water Exchange in Bis(Nitrato)Diaquodioxouranium(VI)

Autor: Emilia, M., Azenha, D. G., Burrows, Hugh, Formosinho, Sebastiao, Gil, Victor, Miguel, Maria Da Graca
Zdroj: Journal of Coordination Chemistry; July 1991, Vol. 24 Issue: 1 p15-18, 4p
Abstrakt: Kinetics of water exchange of bis(nitrato)diaquodioxouranium(VI) in 96.7% acetone-water have been studied by 1H NMR spectroscopy, and the activation parameters ΔH* = 21.0 kJ mol-1, ΔS* = -86.5 J K-1 mol-1 determined.
Databáze: Supplemental Index