Assignment of the 1H and 13C NMR spectra of anthraquinone glycosides from Rhamnus frangula

Autor: Francis, G. W., Aksnes, D. W., Holt, Ø.
Zdroj: Magnetic Resonance in Chemistry; October 1998, Vol. 36 Issue: 10 p769-772, 4p
Abstrakt: 1H and 13C NMR chemical shifts are reported for five anthraquinone glycosides from Rhamnus frangula (Alder Buckthorn). The investigation utilized data obtained by a variety of 1D and 2D NMR techniques such as homodecoupling, NOE, J-modulated spin-echo, COSY, HSC and COLOC. Assignments were made for frangulin A and B and glucofrangulin A and B. A further compound previously thought to be a glycoside of emodin is shown to be physcion-8-O-β-D-glucoside. © 1998 John Wiley & Sons, Ltd.
Databáze: Supplemental Index