Isolation and spectroscopic characterisation of C60F18CF2, the first difluoromethano[60]fullerene

Autor: Avent, Anthony G., Boltalina, Olga V., Lukonin, Andrei Yu, Street, Joan M., Taylor, Roger
Zdroj: Journal of the Chemical Society, Perkin Transactions 2; January 1, 2000, Vol. 2000 Issue: 1 p1-3, 3p
Abstrakt: From the fluorination of [60]fullerene by K2PtF6 at 465 °C under 0.1 bar, we have isolated and characterised C60F18CF2 which has C>s symmetry and is isostructural with C60F18O; it co-elutes (HPLC) with a minor unsymmetrical isomer.
Databáze: Supplemental Index