Isolation and spectroscopic characterisation of C60F18CF2, the first difluoromethano[60]fullerene
Autor: | Avent, Anthony G., Boltalina, Olga V., Lukonin, Andrei Yu, Street, Joan M., Taylor, Roger |
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Zdroj: | Journal of the Chemical Society, Perkin Transactions 2; January 1, 2000, Vol. 2000 Issue: 1 p1-3, 3p |
Abstrakt: | From the fluorination of [60]fullerene by K2PtF6 at 465 °C under 0.1 bar, we have isolated and characterised C60F18CF2 which has C>s symmetry and is isostructural with C60F18O; it co-elutes (HPLC) with a minor unsymmetrical isomer. |
Databáze: | Supplemental Index |
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