Podand-porphyrins with peripheral chelates

Autor: Mel'nik, V. I., Zhilina, Z. I., Andronati, S. A., Ganevich, V. N., Babchinskaya, M. V.
Zdroj: Chemistry of Heterocyclic Compounds; April 1991, Vol. 27 Issue: 4 p376-380, 5p
Abstrakt: Alkylation of 5-(3'-nitro-4'-hydroxyphenyl)-10,15,20-triphenylporphyrin with chloropyridines[2,6-dichloromethyl-and 2-chloromethyl-6-(2'-nitrophenoxymethylpyridine)] as well as condensation by a mixed-aldehyde method starting with formylpyridines [2-(2'-nitro-4'-formylphenoxymethyl)-6-(2'-nitrophenoxy-methyl-) or 2,6-di(2'-nitro-4'-formylphenoxymethyl)pyridine], benzaldehyde, and pyrrole are used to synthesize previously unknown podand-porphyrins containing from one to four peripheral chelates.
Databáze: Supplemental Index