Joint catalytic activation of CO2 and NH2 in reaction with butadiene under the action of palladium complexes

Autor: Dzhemilev, U. M., Kunakova, R. V., Sidorova, V. V.
Zdroj: Russian Chemical Bulletin; February 1987, Vol. 36 Issue: 2 p362-364, 3p
Abstrakt: 1.The possibility of joint catalytic activation of small molecules (CO2 and NH3) has been demonstrated in their reaction with butadiene with the participation of palladium complexes, the products being mono- and bis-(2,7-octadienyl)formamides.2.It has been found that 2-pyrrolidone can take part in a telomerization reaction with butadiene in solutions containing palladium complexes, ammonia and carbon dioxide with the formation of N-2,7-octadienylpyrrolidone.
Databáze: Supplemental Index