Reaction of 1H-1-oxo-2,4,6,8-tetrakis(tert-butyl) phenoxazine with certain group II–IV metals

Autor: Karsanov, I. V., Ivakhnenko, E. P., Khandkarova, V. S., Rubezhov, A. Z., Okhlobystin, O. Yu., Minkin, V. I., Prokof'ev, A. I., Kabachnik, M. I.
Zdroj: Russian Chemical Bulletin; January 1987, Vol. 36 Issue: 1 p60-64, 5p
Abstrakt: 1.In the reaction of 1H-1-oxo-2,4,6,8-tetrakis(tert-butyl)phenoxazine with amalgams of the II–IV group metals, paramagnetic complexes are formed of mono-, bi- and triradical types, according to the nature of the reacting metal.2.Monoradical complexes with Al are formed as a result of successive hydrolysis of the triradical by traces of moisture.
Databáze: Supplemental Index