| Autor: |
Nazarova, N. M., Kopyttsev, Yu. A., Shcherbakova, S. I., Freidlin, L. Kh. |
| Zdroj: |
Russian Chemical Bulletin; November 1975, Vol. 24 Issue: 11 p2475-2477, 3p |
| Abstrakt: |
1.The system PdCl2·(N-methyl-2-pyrrolidone)2-NaBH4 catalyzes the reduction of nitro-benzene to aniline under mild conditions, bypassing the, intermediate formation of the partial hydrogenation products. The rate of reducing the nitro group in o-nitrotoluene is 20 times slower than in nitrobenzene.2.Phenylhydroxylamine, azoxybenzene, and azobenzene are reduced to hydrazobenzene in the presence of the studied catalytic system, which is not hydrogenated further. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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