Synthesis and thermal decomposition of haloalkoxy-sym-triazines. 11. Synthesis and thermolysis of 2-(2-chloroethoxy)-4-N-methyl-N-methoxyamino-6-dimethylamino-sym-triazine

Autor: Dovlatyan, V. V., Pivazyan, V. A., Éliazyan, K. A., Mirzoyan, R. G.
Zdroj: Chemistry of Heterocyclic Compounds; August 1985, Vol. 21 Issue: 8 p942-945, 4p
Abstrakt: 2-(2-Chloroethoxy)-4-N-methyl-N-methoxyamino-6-dialkylamino-sym-triazines were synthesized. In the case of the dimethylamino derivative it was established that thermolysis gives a mixture of oxooxazolo- and oxoimidazo-sym-triazines, the structures of which were proved by data from the IR, PMR, and mass spectra. A probable scheme for the rearrangement-cyclization reaction is proposed.
Databáze: Supplemental Index