1H and13C NMR spectrum-structure correlations for a series of polyene compounds

Autor: Kurkovskaya, L., Genkina, N., Shugol, V.
Zdroj: Journal of Structural Chemistry; July 1995, Vol. 36 Issue: 4 p638-642, 5p
Abstrakt: Abstract: Based on the results of NMR studies of series of polyene compounds Ph(CH=CH)nCH=CXY (X, Y are acceptor substituents), it is suggested that the ratio of vicinal spin-spin coupling constants of protons at the neighboring CH=CH and CH-CH bonds of the same chain be used as a criterion for the degree of charge transfer (equalization of bonds). Conditions (n, X, Y) have been determined under which the ratio is minimal.
Databáze: Supplemental Index