Autor: |
Kurkovskaya, L., Genkina, N., Shugol, V. |
Zdroj: |
Journal of Structural Chemistry; July 1995, Vol. 36 Issue: 4 p638-642, 5p |
Abstrakt: |
Abstract: Based on the results of NMR studies of series of polyene compounds Ph(CH=CH)nCH=CXY (X, Y are acceptor substituents), it is suggested that the ratio of vicinal spin-spin coupling constants of protons at the neighboring CH=CH and CH-CH bonds of the same chain be used as a criterion for the degree of charge transfer (equalization of bonds). Conditions (n, X, Y) have been determined under which the ratio is minimal. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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