| Autor: |
Caro, D. de, Bradley, J. S. |
| Zdroj: |
Langmuir; January 20, 1998, Vol. 14 Issue: 2 p245-247, 3p |
| Abstrakt: |
Infrared spectra are reported of 12CO and 12CO/13CO mixtures adsorbed on colloidal platinum with a mean particle size of 15 Å, stabilized in liquid dispersion by polyvinylpyrrolidone. A shift to higher frequency with increasing coverage of 12CO is observed in the high-frequency (on-top) CO band, and for 12CO/13CO mixtures at maximum coverage a shift of frequencies of the two components of the on-top CO stretching mode is observed with changing 12CO/13CO ratio. These results are due to the presence of vibrational coupling between adsorbed CO molecules on the colloidal platinum particles. The correspondence between these observations and similar results on supported platinum particles and platinum single-crystal faces suggests that, even in the presence of solvent and dissolved polymer, the colloidal metal particles can react with CO to give adsorbed overlayers with significant similarity to those resulting from CO adsorption on clean metal surfaces. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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