| Autor: |
Joe Otsuki, Yusaku Kobayashi, Takumi Torisawa, Tomoo Furuhashi, Yoshinao Shinozaki, Kosuke Sugawa, Yoshiyuki Kojima, Hiroki Yoshikawa, Arata Tsukamoto, Makoto Tadokoro |
| Zdroj: |
Chemistry Letters; Sep2024, Vol. 53 Issue 9, p1-5, 5p |
| Abstrakt: |
This study reports on the multiresponsive behavior of Co(II) bis(tolylterpyridine) nitrate crystals. Each crystal contains a single Co(II) complex and can accommodate up to 4 H2O molecules per asymmetric unit. In its fully hydrated form, the crystal contains planar hexameric hydrogen-bonded H2O clusters. The adsorption and desorption of H2O occur reversibly with changes in humidity, despite the absence of extended H2O channels. Furthermore, the crystals exhibit a crystal-to-crystal thermal phase transition. The structural studies reveal the dynamic nature of these crystals, which contribute to their multiresponsive behavior. [ABSTRACT FROM AUTHOR] |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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